Binkilic -- oxide and carbonate ore

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Location - Turkey, Black Sea region

Age (of protore) - 28 Ma

Original size - 0.3 million tonnes of Mn

References

Gültekin AH, Balcı N (2018) Geochemical Characteristics of Sedimentary Manganese Deposit of Binkılıç, Trache Basin, Turkey. J Geol Geophys 7: 336. doi: 10.4172/2381-8719.1000336

Öztürk, H., and Frakes, L.A., 1995, Sedimentation and diagenesis of an Oligocene manganese deposit in a shallow
subbasin of the Parathethys: Thrace Basin, Turkey: Ore Geology Reviews, v. 10, p. 117-132.

Gultekin, Ali Haydar, 1998, Geochemistry and origin of the Oligocene Binkilic manganese deposit; Thrace Basin, Turkey: Turkish Journal of Earth Sciences, V. 7, p. 11-24

 

major elements - trace elements - rare-earth elements - REE normalized - isotopes

Major Elements, oxide ores, hostrocks

 

 

 

%

%

%

%

%

%

%

%

%

%

%
MnO
Fe2O3t
SiO2
Al203
CaO
MgO
K2O
Na2O
P205
 TiO2
LOI

Average

 
Mn ore - oxide
 55.4 2.7 7.0 2.3 14.5 0.9 0.3 0.5 0.7 0.5 13.2
5-Oz high-grade, oxide 69.2 0.10 7.70 1.10 0.90 0.10 0.40 0.60 0.03 0.25 14.1
7-Oz high-grade, oxide 67.9 1.80 2.70 1.00 1.10 0.30 0.30 0.60 0.06 0.40 16.0
8-Oz high-grade, oxide 57.8 1.00 11.1 2.20 1.60 0.10 0.70 0.60 0.09 0.34 15.0
5-Gu high-grade, oxide 56.3 4.06 5.42 1.18 16.37 1.21 0.23 0.20 0.61 0.31 13.2
8-Gu high-grade, oxide 55.8 1.07 6.60 5.17 14.64 1.10 0.38 0.13 1.07 1.07 12.9
BM12 massive 66.1 2.54 3.93 1.13 6.74 1.33 0.17 0.58 0.25 0.8 16.9
BOP05 pisolitic 55.0 3.97 7.3 1.15 17.0 1.18 0.22 0.20 0.60 0.20 13.0
BOP08 pisolitic 55.0 1.05 6.5 5.1 14.4 1.08 0.37 0.13 1.05 0.90 14.4
3-Gu high-grade, oxide 54.0 3.14 9.85 1.41 15.9 1.14 0.35 0.44 0.99 0.33 12.4
BM14 massive 53.5 3.49 5.93 0.98 18.8 1.21 0.42 0.32 0.59 0.17 14.6
BOP03 pisolitic 53.2 3.69 9.69 1.39 16.6 1.12 0.34 0.43 0.97 0.30 12.2
10-Gu high-grade, oxide 51.6 2.68 6.66 2.63 21.9 0.97 0.40 0.36 0.79 0.61 11.2
BOP10 pisolitic 50.9 2.65 6.57 2.6 21.6 0.96 0.39 0.36 0.78 0.41 12.7
6-Gu high-grade, oxide 49.7 2.94 7.10 2.64 22.3 0.72 0.33 0.87 0.96 0.51 11.3
BOP04 pisolitic 49.0 4 4.01 3.5 17.5 1.04 0.24 0.50 1.10 0.50 11.5
BM15 massive 49.0 2.9 7 2.6 22.0 0.71 0.33 0.86 0.95 1.05 12.6
4-Gu high-grade, oxide 47.7 4.06 10.1 3.55 17.7 1.05 0.24 0.51 1.12 0.61 10.7
7-Gu high-grade, oxide 44.8 2.53 15.3 0.99 19.8 1.33 0.18 0.27 0.91 0.20 12.8
BM18 massive 44.3 2.5 8.17 0.98 19.6 1.31 0.18 0.27 0.90 1.10 13.7
9-Gu high-grade, oxide 39.9 8.19 7.71 8.14 16.2 0.93 0.35 0.40 0.97 1.11 15.8
                         
BD25 detritus rich 15.0 2.5 35.3 16.32 19.0 0.8 0.4 0.90 0.25 1.32 7.0
1-Gu low-grade, oxide 13.4 2.58 37.5 15.80 18.6 0.82 0.41 0.93 0.26 1.19 8.3
2-Gu low-grade, oxide 11.1 8.90 25.3 9.00 32.0 0.66 1.11 0.81 0.44 0.08 10.1
BD27 detritus rich 11.0 8.8 25.1 8.9 31.7 0.65 1.1 0.88 0.44 1.01 10.9
11-Oz fish beds shale 0.10 6.2 49.4 15.5 4.9 3.000 2.2 0.60 0.65 0.18 23.2

Major Elements, carbonate ores, hostrocks

 

 

 

%

%

%

%

%

%

%

%

%

%

%
MnO
Fe2O3t
SiO2
Al203
CaO
MgO
K2O
Na2O
P205
 TiO2
LOI

Average

 
Mn ore - oxide
 36.3 4.7 8.7 2.2 16.9 0.9 0.5 0.3 0.2 0.3 25.4
3-Oz high-grade, carbonate 51.2 1.20 12.1 3.00 6.60 1.10 0.60 0.40 0.14 0.22 26.8
4-Oz high-grade, carbonate 46.3 2.50 13.2 3.50 6.20 2.40 0.60 0.20 0.16 0.27 21.2
12-Oz high-grade, carbonate 37.9 12.7 2.50 0.60 16.8 0.40 0.10 0.10 0.06 0.30 22.5
9-Oz high-grade, carbonate 32.7 0.40 4.30 0.90 20.0 0.30 0.10 0.10 0.04 0.25 34.6
6-Oz high-grade, carbonate 32.2 2.00 7.60 2.10 20.3 0.30 0.90 0.40 0.08 0.44 24.6
10-Oz low-grade, carbonate 29.7 1.40 12.2 3.00 21.9 0.40 0.80 0.50 0.11 0.35 25.4
11-Gu low-grade, carbonate 24.1 12.5 9.14 2.22 26.2 1.36 0.61 0.21 0.67 0.16 22.5
12-Gu low-grade, carbonate 18.4 7.46 12.2 7.21 16.9 0.92 0.10 0.56 0.59 0.42 36.1
13-Gu low-grade, carbonate 16.2 0.73 3.35 0.94 46.9 1.57 0.42 0.10 0.63 0.31 27.7
1-Oz footwall LS 0.1 0.2 2.2 0.5 53.6 0.4 0.1 0.1 0.02 0.13 42.5
2-Oz footwall LS 4.1 0.6 2.2 0.4 48.9 0.8 0.1 0.1 0.03 0.66 40.2
13-Oz hangingwall LS 1.00 2.00 11.3 3.3 43.7 0.9 0.4 0.2 0.15 0.25 38.0

 

Trace elements, oxide ores, ppm

 

 

ppm

ppm

ppm

ppm

ppm

ppm

ppm

ppm

ppm

ppm

ppm

ppm

ppm

ppm

ppm

ppm

ppm

ppm

ppm

 
As
Ba
Cd
Co
Cr
Cu
Mo
Nb
Ni
Pb
Rb
Sc
Sr
Th
U
V
Y
Zn
Zr
avg
na
 4442   73 15 80     183 42     1959     62 14 60 46
5-Oz
9133 52 12 13 41 77 13 37 17
7-Oz
14148 83 1.0 21 91 122 14 44 15
8-Oz
17461 43 9.8 9.2 7.1 139 15 28 29
5-Gu
2448 94 13 95 375 51 376 42 15 65 66
8-Gu
2196 55 20

120

 340 68 588 35 10 40 49
BM12
2115 90 12 105 115 36 25 3638 20 12 68 48
BOP05
2548 94 13 95 109 51 27 2305 42 43 65 66
BOP08
1450 55 20 120 140 68 19 5980 35 9 50 49
3-Gu
2616 149 15 120 330 53 490 30 10 85 65
BM14
810 62 17 85 64 40 8 350 65 11 47 26
BOP03
2216 149 15 120 350 53 21 !010 30 10 85 65
10-Gu
2814 96 16 112 275 56 487 33 16 75 60
BOP10
2814 96 16 112 275 56 19 4530 33 17 75 60
6-Gu   3269 85 18 103 270 38   437 31 8 60 57
BOP04   3106 95 15 98 36 33 35 5760 18 34 71 63
BM15   3269 85 18 103 90 38 21 3760 31 8 60 57
4-Gu   3106   95 15 98     360 33     316     18 5 71 63
BD25   2130 42 4 68 216 27 5 168 10 3 40 42
7-Gu   2251 65 16 110 310 42   522 28 12 45 66
BM18   4251 65 16 110 66 42 24 5608 28 13 45 66
9-Gu   2967 90 14 106 260 30   563 21 13 80 73
1-Gu   2130 42 4 68 216 27   430 10 3 67 42
2-Gu   3092 64 19 83 90 40   743 67 13 42 33
BD27   780 64 19 83 64 40 10 379 67 13 42 33
11-Oz   269 85 198 124 496       244 23 229 110

blank or nr = not reported; bd = below detection

Rare-earth elements, ppm

 
Sample
La
Ce
Pr
Nd
Sm
Eu
Gd
Tb
Dy 
Ho 
Er 
Tm 
Yb
Lu
avg 16 26 nr 12 3 3 nr 1 2 nr nr nr 1.6 nr
5-Oz 10.00 17.00 9.00 2.00 2.00 1.00 1.00
7-Oz 12.00 23.00 9.00 2.00 3.00 1.00 1.00
8-Oz 17.00 25.00 14.00 3.00 4.00 1.00 1.00
5-Gu
8-Gu
BM12 16.51 22.32 10.78 2.78 1.88 1.75 0.70 0.72 0.59 0.65 0.09
BOP05 43.33 52.11 27.55 5.59 2.19 5.50 3.40 3.61 3.13 3.23 0.47
BOP08 39.11 13.12 8.23 1.88 0.86 0.65 1.86 0.56 0.62 0.85 0.02
3-Gu
BM14 10.00 15.60 9.62 2.01 2.00 0.74 0.45 0.72 0.80 0.81 0.02
BOP03 21.01 24.34 14.11 3.02 2.22 3.15 0.67 0.71 2.05 2.13 0.18
10-Gu
BOP10 12.00 25.07 11.89 2.95 1.78 0.76 0.75 3.01 2.02 1.85 0.28
6-Gu
BOP04 26.25 45.01 20.22 5.05 4.09 4.52 0.98 3.99 3.32 3.44 0.41
BM15 12.20 20.02 10.10 3.05 2.04 2.11 0.99 1.88 0.86 0.78 0.03
4-Gu                            
7-Gu
BM18 15.32 21.43 7.89 3.11 1.87 0.81 1.23 2.00 1.65 1.87 0.03
9-Gu
BD25 5.10 6.22 2.98 0.67 0.32 0.45 0.33 0.40 0.52 0.32 0.03
1-Gu
2-Gu
BD27 8.90 9.91 3.65 0.78 0.74 0.69 0.64 0.65 0.55 0.60 0.15
11-Oz 7.00 54.00 27.00 5.00 1.00 1.00 3.00 3.00

Rare-earth elements,

normalized to chondritic values of Taylor & McLennan (1992)
Sample
LaN
CeN
PrN
NdN
SmN
EuN
GdN
TbN
YbN
Ce/Ce*
Eu/Eu*
LaN/YbN
avg 46.1 26.3 23.4 17.3 12.7 24.1     6.0 0.801   7.681 0.851 1.592 7.9806
5-Oz 27.25 17.76 16.34 12.66 8.66 22.99 4.03 0.84 6.76
7-Oz 32.70 24.03 17.37 12.66 8.66 34.48 4.03 1.01 8.11
8-Oz 46.32 26.12 26.19 19.69 12.99 45.98 4.03 0.75 11.49
5-Gu
8-Gu
BM12 44.99 23.32 21.79 15.16 12.03 21.61 5.72 12.07 2.62 0.74 2.60 17.16
BOP05 118.07 54.45 56.17 38.75 24.20 25.17 17.97 58.62 13.02 0.67 1.21 9.07
BOP08 106.57 13.71 24.26 11.58 8.14 9.89 2.12 32.07 3.43 0.27 2.38 31.09
3-Gu
BM14 27.25 16.30 17.09 13.53 8.70 22.99 2.42 7.76 3.27 0.76 5.01 8.34
BOP03 57.25 25.43 28.25 19.85 13.07 25.52 10.29 11.55 8.59 0.63 2.20 6.67
10-Gu
BOP10 32.70 26.20 20.91 16.72 12.77 20.46 2.48 12.93 7.46 1.00 3.63 4.38
6-Gu  
BOP04 71.53 47.03 38.67 28.44 21.86 47.01 14.77 16.90 13.87 0.89 2.62 5.16  
BM15 33.24 20.92 18.86 14.21 13.20 23.45 6.90 17.07 3.15 0.84 2.46 10.57  
4-Gu                              
7-Gu      
BM18 41.74 22.39 17.26 11.10 13.46 21.49 2.65 21.21 7.54 0.83 3.60 5.54      
9-Gu      
BD25 13.90 6.50 6.25 4.19 2.90 3.68 1.47 5.69 1.29 0.70 1.78 10.77  
1-Gu  
2-Gu  
BD27 24.25 10.36 8.61 5.13 3.38 8.51 2.25 11.03 2.42 0.72 3.08 10.02  
11-Oz 19.07 56.43 30.19 37.97 21.65 11.49 18.60 17.24 12.10 2.35 0.57 1.58  

Isotopes
      calcite rhod Corg calcite calcite rhod rhod      
Sample
 TC % TOC % δ13C pdb δ13C pdb δ13C pdb δ18O pdb δ18O smow δ18O pdb δ18O smow Stotal % δ34S sulfide 87Sr/86Sr
avg    
           
.
  
5-Oz    
           
 
7-Oz                        
8-Oz                        
5-Gu    
     
8-Gu    
     
BM12    
                 
BOP05    
                 
BOP08    
                 
3-Gu            
BM14                        
BOP03                        
10-Gu    
     
BOP10    
           
 
6-Gu            
BOP04                        
BM15                        
4-Gu            
7-Gu            
BM18                        
9-Gu                        
BD25                        
1-Gu            
2-Gu            
BD27                        
11-Oz